DOI: 10.1055/s-00000083

Synlett

Ausgabe 01 · Volume 2009 · Januar 2009 DOI: 10.1055/s-002-14728

Editorial

I
Editorial

account

1
Chapyshev, Sergei V.: Selective Reactions on the Azido Groups of Aromatic Polyazides
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9
El Kharrat, Salem; Laurent, Philippe; Blancou, Hubert: The Stability/Reactivity Effects of Trifluoromethyl and Perfluoroalkyl Chains in a Masked 1,3-Dicarbonyl Derivative: The Case of 1-Acetoxy-1-iodo-2-(perfluoroalkyl)ethanes
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letter

23
Morton, Jason G. M.; Kwon, Laura D.; Freeman, John D.; Njardarson, Jon T.: Thieme Chemistry Journal Awardees - Where are They Now? Efforts towards the Total Synthesis of Vinigrol
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Supporting Information
28
Sato, Akinori; Yorimitsu, Hideki; Oshima, Koichiro: Thieme Chemistry Journal Awardees - Where are They Now? Regio- and Stereoselective Radical Additions of Thiols to Ynamides
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32
Srikrishna, A.; Ravi, G.; Venkata Subbaiah, D. R. C.: Enantioselective First Total Syntheses of 2-(Formylamino)trachyopsane and ent-2-(Isocyano)trachyopsane via a Biomimetic Approach
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35
Asano, Keisuke; Matsubara, Seijiro: N-Alkylimidazole as Amphiphilic Organocatalyst: ‘Catalytic’ Morita-Baylis-Hillman Reaction on Water without Organic Solvent
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39
Jung, Ji-Young; Taher, Abu; Kim, Hyun-Jin; Ahn, Wha-Seung; Jin, Myung-Jong: Heck Reaction Catalyzed by Mesoporous SBA-15-Supported Ionic Liquid-Pd(OAc)2
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43
Yadav, Jhillu S.; Gayathri, Kamakolanu Uma; Reddy, Basi V. Subba; Prasad, Attaluri R.: Modular Total Synthesis of Lamellarin G Trimethyl Ether
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47
Cardullo, Francesca; Donati, Daniele; Merlo, Giancarlo; Paio, Alfredo; Petricci, Elena; Taddei, Maurizio: Microwave-Assisted Aminocarbonylation of Aryl Bromides at Low Carbon Monoxide Pressure
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51
Bertolini, Ferruccio; Woodward, Simon: Rapid 1,4-Alkynylation of Acyclic Enones Using K[F3BCCR]
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55
Khoshkholgh, Malihe Javan; Balalaie, Saeed; Bijanzadeh, Hamid Reza; Gross, Jürgen H.: Copper(I) Iodide Catalyzed Domino Knoevenagel Hetero-Diels-Alder Reaction of Terminal Acetylenes: Synthesis of Pyrano[2,3-c]pyrazoles
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59
Donald, James R.; Taylor, Richard J. K.: Tandem Meinwald Rearrangement-Fischer Indolisation: A One-Pot Conversion of Epoxides into Indoles
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63
Sluiter, Jonas; Christoffers, Jens: Synthesis of 1-Methylbenzimidazoles from Carbonitriles
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67
Rauhut, Christian B.; Cervino, Christian; Krasovskiy, Arkady; Knochel, Paul: Stereoselective Preparation of Cyclopropylmagnesium Reagents via a Br-Mg Exchange Using i-PrMgCl×LiCl in the Presence of Dioxane
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71
Hanessian, Stephen; Riber, Ludivine; Marin, Julien: Diastereoselective Synthesis of Functionally Diverse Substituted Pipecolic ­Acids
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75
Vale, Juliana A.; Zanchetta, Daniel F.; Moran, Paulo J. S.; Rodrigues, J. Augusto R.: Efficient α-Methylenation of Carbonyl Compounds in Ionic Liquids at Room Temperature
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79
Park, Hee Joong; Lee, Jong Chan: Oxidation of Benzylic Alcohols with Urea-Hydrogen Peroxide and Catalytic Magnesium Bromide
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81
Cho, Chang Ho; Lee, Jin Young; Kim, Sunggak: Radical Cyanation of Alkyl Iodides with Diethylphosphoryl Cyanide
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85
Kuroboshi, Manabu; Kobayashi, Ryoto; Nakagawa, Takayuki; Tanaka, Hideo: Electroreductive Generation of Recyclable Organic Reductant from N,N′-Dioctyl-4,4′-bipyridinium and Pd-Catalyzed Reductive Coupling of Aryl Halides
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89
Feray, Laurence; Perfetti, Patricia; Bertrand, Michèle P.: Mild Stereoselective Hydrohalogenation Leading to (Z)-Halopropenamides at Room Temperature
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92
Hajbi, Youssef; Suzenet, Franck; Khouili, Mostafa; Lazar, Said; Guillaumet, Gérald: General Synthetic Approach to 4-Substituted 2,3-Dihydrofuro[2,3-b]pyridines and 5-Substituted 3,4-Dihydro-2H-pyrano[2,3-b]pyridines
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97
Grigg, Ronald; Somasunderam, Anoma; Sridharan, Visuvanathar; Keep, Ann: Palladium-Catalysed Cascades Triggered by Dehydrogenation of Secondary or Tertiary Amines: Access to Bridged- and Fused-Ring Heterocycles
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100
Lundhaug, Kamilla; Skattebøl, Lars; Aasen, Arne Jørgen: Synthesis of (1S,3R,5R,7S)-Sordidin, the Main Component of the Aggregation Pheromone of the Banana Weevil Cosmopolites sordidus
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103
Cordaro, Massimiliano; Grassi, Giovanni; Risitano, Francesco; Scala, Angela: A New Construction of Diversely Functionalized Oxazoles from Enolizable Cyclic 1,3-Dicarbonyls and 5(4H)-Oxazolones
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106
Hugenberg, Verena; Haufe, Günter: Oxidative Desulfurization-Difluorination of Alkyl Aryl Thioethers: Synthesis of ω-Substituted 1,1-Difluoroalkanes
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109
Sälinger, Daniel; Brückner, Reinhard: High-Yielding Large-Scale Syntheses of Enantiomerically Pure NOBIN and a NOBIN-Based Enantiomerically Pure NHC Precursor
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112
Gillis, H. Martin; Greene, Lana; Thompson, Alison: Preparation of Sulfenyl Pyrroles
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Supporting Information
117
Ojha, Lawanya R.; Kudugunti, Shashi; Maddukuri, Padma P.; Kommareddy, Amitha; Gunna, Meena R.; Dokuparthi, Praveen; Gottam, Hima B.; Botha, Kiran K.; Parapati, Divya R.; Vinod, Thottumkara K.: Benzylic Carbon Oxidation by an in situ Formed o-Iodoxybenzoic Acid (IBX) Derivative
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122
Arai, Masaki; Miyauchi, Yayoi; Miyahara, Tadashi; Ishikawa, Teruhiko; Saito, Seiki: Synthesis of 4-Acetoxyindoles and Related Derivatives by Means of Air Oxidation of 4-Oxo-4,5,6,7-tetrahydroindoles Obtained from Nitroalkenes and Cyclohexane-1,3-diones
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Supporting Information

cluster

129
Lovely, Carl J.; Flores, Jaime A.; Meng, Xiaofeng; Dias, H. V. Rasika: Silver-Catalyzed C-H Insertion Reactions with Donor-Acceptor Diazoacetates
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133
Pillekamp, Marcus; Aniol, Alexandra; Heppekausen, Johannes; Neukirchen, Saskia; Seel, Stephanie; Oppel, Iris M.; Dyker, Gerald: Palladium-Catalyzed Four-Membered Ring Annelation Reactions at Dibenzobarrelene
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138
Yoo, Woo-Jin; Correia, Camille A.; Zhang, Yuhua; Li, Chao-Jun: Oxidative Alkylation of Cyclic Benzyl Ethers with Malonates and Ketones Using Oxygen as the Terminal Oxidant
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143
Zalatan, David N.; Du Bois, J.: Oxidative Cyclization of Sulfamate Esters Using NaOCl - A Metal-Mediated Hoffman-Löffler-Freytag Reaction
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147
Harrisson, Peter; Morris, James; Steel, Patrick G.; Marder, Todd B.: A One-Pot, Single-Solvent Process for Tandem, Catalyzed C-H Borylation-Suzuki-Miyaura Cross-Coupling Sequences
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151
Nadeau, Etienne; Li, Zhanjie; Morton, Daniel; Davies, Huw M. L.: Rhodium Carbenoid Induced Intermolecular C-H Functionalization at Tertiary C-H Bonds
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spotlight

155
Amarante, Giovanni Wilson: Ozone: A Versatile Oxidizing Agent in Academic Syntheses and Industrial Processes
157
Iglesias-Sigüenza, Francisco Javier: Carbon Disulfide (CS2)

addenda and errata

e1
Oxidative Desulfurization-Difluorination of Alkyl Aryl Thioethers:
Synthesis of ω-Substituted 1,1-Difluoroalkanes