DOI: 10.1055/s-00000131

Synfacts

Issue 10 · Volume 20 · October 2024 DOI: 10.1055/s-014-60265

Synform

A149
Zanda, Matteo: SYNFORM ISSUE 2024/10

Synthesis of Natural Products

z1011
All PDFs of this category
1011
Total Synthesis of (–)-Rauvomine B
1012
Synthesis of (+)-Kalmanol
1013
Synthesis of (–)-Griseoviridin
1014
Total Synthesis of (–)-Platensilin
1015
Total Synthesis of (–)-Crinipellin A and B
1016
Total Synthesis of (±)-Baphicacanthcusine A
1017
A Formal Synthesis of (±)-Morphine

Synthesis of Heterocycles

z1019
All PDFs of this category
1019
Substituent-Directed Cycloisomerization Reduction Cascade for Synthesizing Oxacycles
1020
Using Bench-Stable 2-Mercaptothiazolinium Salts for the Photoredox Alkylation of N-Heteroarenes
1021
Nickel-Mediated Skeletal Editing: Internal ‘O’-to-‘N’ Exchange of Oxazoles and Oxadiazoles
1022
Ring Expansion of Pyrroles with Concomitant Nitrogen Deletion
1023
Synthesis of Functionalized Pyrrolidines and Piperidines
1024
Simple Two-Step Protocol for the Synthesis of Amino-Oxetanes
1025
Regioselective Approach to (Z)-5-Methylene-morpholin-2-ones from Amino Acids and Enones
1026
Multigram Synthesis of Diastereomerically Pure 3-Substituted 6-Azacyclo[3.3.1]heptane Derivatives
1027
Synthesis and Property Analysis of Monocyclic B–OH Diazaborines
1028
Atom Transmutation Converting Pyridines into Substituted Benzene Derivatives
1029
Formal Reductive Amination of N-Heterocycles through N-Alkenylation/Reduction Sequence
1030
Ru-Mediated Synthesis of Chiral Secondary Alcohols

Synthesis of Materials and Unnatural Products

z1031
All PDFs of this category
1031
A Stable Stannyne
1032
Surface-Initiated HAT-RAFT
1033
Photoreductive Functionalization of Aryl Alkynes
1034
Azaparacyclophanes by One-Step Catalyst-Transfer Macrocyclization
1035
Intramolecular ipso-Arylation via Halogen Atom Transfer
1036
Giant Supramolecular Hexagons
1037
Fusing Twisted Nanobelts with Helicenes
1038
Porphyrin-Diazaporphyrin Molecular Tapes
1039
Visible-Light-Induced Direct C–H Alkylation of Polycyclic Aromatic Hydrocarbons with Alkylsulfones
1040
Fused Koelsch Radical
1041
Thermally Stable, Chemically Recyclable Polymers
1042
Boraphenalenes

Metals in Synthesis

z1043
All PDFs of this category
1043
Copper-Catalyzed Oxidative Hydrofunctionalization of Alkenes
1044
Synthesis of 2-Aminothiozaoles via Photocatalyzed Annulation of Enaminones with Thioureas
1045
Regiodivergent Nickel-Catalyzed Hydrosilylation of α-(Fluoroalkyl)styrenes
1046
Enantioselective Benzylation of Sulfonylimines with para-Methylphenols via a Paired Electrolysis Strategy
1047
Nickel-Catalyzed Regio- and Diastereoselective Hydroalkylation of Alkynyl Boronamides
1048
Enantioselective Carboamination via Palladium Catalysis
1049
A Nickel-Catalyzed Nozaki–Hiyama–Kishi Reaction under Visible Light Photocatalysis
1050
C–C Bond Cleavage of Allylic Alcohols Enabled by a Modified Mukaiyama Hydration
1051
Synthesis of Aryl Sulfonamides by a Sandmeyer-Type Chlorosulfonylation of Anilines
1052
Photocatalyzed Amination of Phenols and Halophenols
1053
Asymmetric Synthesis of Spirocyclic Lactones
1054
Ligand-Controlled Regiodivergent Asymmetric Cascade Hydroboration and Hydroallylation of Terminal Alkynes
1055
Copper-Photocatalyzed Amination of Unactivated Alkyl Halides by Inner-Sphere Single Electron Transfer
1056
Synthesis of Enantioenriched β-Aryl Amino Acids via Palladium/Lewis Acid Relay Catalysis
1057
Iridium-Catalyzed Desymmetrization Enables Access to Distal Biaxial Atropisomers
1058
Single-Carbon Skeletal Editing of Alkenes via Rhodium Catalysis
1059
Nickel-Catalyzed Asymmetric Cross-Hydrodimerization of Enamides and Unactivated Alkenes
1060
Synthesis of Allenylsilanes via Dirhodium(II) Catalysis: An Amine ON-OFF Effect
1061
Kinetic Resolution and DYKAT via Palladium-Catalyzed Asymmetric Allylic Substitution of C(sp3)–C(sp3) Bonds
1062
Silver-Catalyzed Rearrangement of Cyclopropenones to α-Alkylidene Lactones
1063
Dual Bismuth and Nickel-Catalyzed Deoxygenative Arylation of Alcohols Facilitated by the β-Silicon Effect
1064
Synthesis of 1-Fluoro-1-arylcyclopropanes via Stille Cross-Coupling
1065
Asymmetric Synthesis of Sulfur-Stereogenic Sulfilimines by Palladium-Catalyzed Arylation of Sulfenamides
1066
Rhodium-Catalyzed Hydroformylation of Cyclopropenes
1067
Dual Iron and Nickel-Catalyzed Photoelectrochemical C–C Functionalization of Alcohols
1068
Synthesis of N-Aryl-oxamic Acids via Copper Catalysis

Polymer-Supported Synthesis

z1069
All PDFs of this category
1069
Aerobic Dehydrogenation of Hydrazones to Diazo Compounds with a Fe–N–C Catalyst
1070
Aerobic Photooxidative Amidation of Aldehydes and Amines with a Triazine-Based COF
1071
Triazine COF for the Photocatalytic Aerobic Oxidation of Toluenes
1072
Reduction of Nitroarenes to Anilines Using H2S as a Hydrogen Donor by a Ceria-Supported Iron Composite
1073
Enantioselective Electrophilic Amination of Active Methine Compounds Using Chiral COFs
1074
Palladium Nanoparticles Supported by Co-Ferrite Bearing Arginine-Triazine Units for Aryl Cyanation
1075
N,P co-Doped Carbon Materials Derived from Yeast for Selective Reduction of Halogenated Nitrobenzenes
1076
Synthesis of Spiro-Thiazolone-Tetrahydrothiophenes Using a Polystyrene-Supported Amine Catalyst
1077
Selective Semi-Hydrogenation of Alkynes Catalyzed by a Bimetallic Ag and Cu Single-Atom on g-C3N4
1078
Photocatalytic Oxidation of Sulfides by Perovskite Cs3Bi2Br9/TiO2 Composites
1079
Selective Reduction of Nitroolefins to Nitroalkanes Using Frustrated Lewis Pairs Modified NU-1000 MOF
1080
Hydroboration of Alkynes and Alkenes Using a Core-Shell Copper Nanocluster

Organo- and Biocatalysis

z1081
All PDFs of this category
1081
A Novel Trifunctional Catalyst Enables Radical–Radical Coupling via Intramolecular Frustrated Lewis Pairs
1082
Remote C–H Functionalization via Radical NHC Organocatalysis
1083
Peptide-Catalyzed Kinetic Resolution of β-Branched Aldehydes
1084
A Novel Electrophilic Cyanation through Phosphonium Activation of Isocyanates
1085
Inverse Hydride Shuttle Catalysis Enables the Stereoselective Synthesis of Azabicycles
1086
Carbonic Anhydrase: Zinc-Based Enzyme as a Catalyst for Enantioselective Reduction of Dialkyl Ketones
1087
Asymmetric Base-Catalyzed Tetrahydrofuran Synthesis from Cyclopropanes and Carbonyl Compounds
1088
Chiral Phosphoric Acid-Catalyzed Synthesis of 3-Hydroxyindolenines and 3-Oxindoles
1089
Enantioselective Relay Coupling of Perfluoroalkyl and Vinylogous Ketyl Radicals
1090
Organocatalytic Asymmetric Synthesis of Si-Stereogenic Silacycles

Innovative Drug Discovery and Development

z1091
All PDFs of this category
1091
Late-Stage O-to-N Molecular Editing of Bilobalide Alters Pharmacology
1092
A Convenient, Stable Alternative to SOF4 for Access to S(VI) Compounds
1093
Exhaustive Deuterium Editing Study of 1,4-Benzodiazepine-2,5-dione Derivatives
1094
Rapid Access to Structurally Diverse α-Amido Aldehydes via Dual Fe/Organo-Catalysis
1095
Three-Component Alkyl Petasis Boron–Mannich Reaction for Accessing C(sp3)-Rich Amines
1096
Streamlined Synthesis of Antibacterial Polycyclic Xanthenes
1097
Photochemical Synthesis of Thioesters from Aryl Halides and Carboxylic Acids
1098
Access to THβC-type Indole Alkaloids via Enantioselective 1,3-Dipolar Cycloaddition
1099
Highly Selective, Scalable, and Green Access to Esomeprazole via Enantioselective Sulfoxidation
1100
Enantioselective Diels–Alder Approach to Cannabinoids
1101
Total Synthesis of Hypersampsone M, an Archetypal Homoadamantane PPAP
1102
Novel Bismuth-Photocatalyzed Cyclopropanation

Peptide Chemistry

z1103
All PDFs of this category
1103
Synthesis of Quaternary α-Amino Acids
1104
Carbon-Isotope-Labeled Amino Acid Synthesis
1105
Rhodium-Catalyzed Macrocyclization of Peptides
1106
3,3-Difluoroallyl Sulfonium Salts Mediated the gem-Difluroallylation of Cysteine Residues in Peptides
1107
Protection of Sterically Hindered Amide of Cyclo-(AA-Gly) Regioselectively Using Triisobutylaluminum
1108
Aldolase-Catalyzed Enantioselective Amino Acid Synthesis from Glycine
1109
Synthesis of 3-Benzyl-β-alanine Using Electrochemical Nickel-Catalyzed C(sp2)–C(sp3) Cross-Coupling
1110
Enantioselective Synthesis of Unnatural Amino Acids by N–H Bond Insertion of Anilines
1111
Epimerization-Free Native Chemical Ligation Using β-Lactone for the Synthesis of Polypeptides
1112
α-Amino Acids by Reductive Carboxylation of Imines Using Formate and CO2
1113
Pd-Catalyzed β-C(sp3)–H Olefination/Cyclization of Methionine-Containing Peptides
1114
Direct Alkylamination of Tyrosine Derivatives Using Fe Catalysis and O-Benzoyl-N,N-dialkylhydroxylamines
1115
Peptide Synthesis Using Unprotected Amino Acids with N-(Z-α-Aminoacyl)benzotriazoles

Flow Chemistry

z1117
All PDFs of this category
1117
Enantioselective Alkylation of Ketones In Flow
1118
Two-Step, Multi-Kilo Synthesis of 4-Methyl-1,2,5-Oxadiazole-3-Carboxylic Acid

Erratum

1119
Carreira, Erick M.; Ruf, Vincent A. P.: Erratum: Synthesis of (–)-Aspersteroid A