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Synfacts 2009(5): 0506-0506
DOI: 10.1055/s-0029-1216572
DOI: 10.1055/s-0029-1216572
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag
Stuttgart ˙ New York
Self-Healing, Dynamic Polymers
P. Reutenauer, E. Buhler, P. J. Boul, S. J. Candau, J.-M. Lehn*
Université de Strasbourg and Université Denis Diderot-Paris, France
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
22. April 2009 (online)
Significance
Dynamic polymers based on the reversible Diels-Alder reaction between monomers M1 or M2 (dienophiles) and M3 (diene) were synthesized and isolated. The mechanical properties of the resulting dynamers could be tailored by changing the feed ratios of the monomers and adding a cross-linker containing four fulvene moieties. The dynamer formed between M2 and M3 was found to be self-healing.