DOI: 10.1055/s-00000083

Synlett

Issue 12 · Volume 2003 · October 2003 DOI: 10.1055/s-002-2820

editorial

I
Editorial

account

1759
Jun, Jong-Gab: Introduction of Bicyclic Ketal Chemistry: Synthesis and Transformation Reaction of 6,8-Dioxabicyclo[3.2.1]octane Skeletal System
https://www.thieme-connect.de/bilder/synlett/200312/a320_ga

letter

1778
Bernardi, Luca; Bonini, Bianca F.; Capitò, Elena; Dessole, Gabriella; Fochi, Mariafrancesca; Comes-Franchini, Mauro; Ricci, Alfredo: A New and Practical Procedure for the Bruylants Reaction. Zinc-Mediated Synthesis of Tertiary Homoallylamines and β-Aminoesters
https://www.thieme-connect.de/bilder/synlett/200312/g146_ga
1783
Schumann, Herbert; Kaufmann, Jens; Schmalz, Hans-Günther; Böttcher, Andreas; Gotov, Battsengel: Pd-Catalyzed Cross-Coupling of Haloarenes and Chloroarene-Cr(CO)3 Complexes with Stabilized Vinyl- and Allylaluminium Reagents
https://www.thieme-connect.de/bilder/synlett/200312/g133_ga
1789
Wu, Yong-Jin; He, Huan: Copper-Catalyzed Cross-Coupling of Aryl Halides and Thiols Using Microwave Heating
https://www.thieme-connect.de/bilder/synlett/200312/s043_ga
1791
Lingard, Iain; Bhalay, Gurdip; Bradley, Mark: Hexadienyloxycarbonyl (Hdoc) - A Mild Acid Labile Protecting Group for Amines
https://www.thieme-connect.de/bilder/synlett/200312/d099_ga
1793
Palaniappan, Srinivasan; Narender, Puli; Saravanan, Chandrasekaran; Rao, Vaidya Jayathirtha: Polyaniline-Supported Sulfuric Acid Salt as a Powerful Catalyst for the Protection and Deprotection of Carbonyl Compounds
https://www.thieme-connect.de/bilder/synlett/200312/d158_ga
1797
Quayle, Peter; Fengas, David; Richards, Stuart: Atom Transfer Radical Cyclisations Mediated by the Grubbs Ruthenium Metathesis Catalyst
https://www.thieme-connect.de/bilder/synlett/200312/d190_ga
1801
Wolf, Christian; Tumambac, Gilbert E.; Villalobos, Cristina N.: Acid-Mediated Halogen Exchange in Heterocyclic Arenes: A Highly Effective Iodination Method
https://www.thieme-connect.de/bilder/synlett/200312/s061_ga
1805
Chakraborti, Asit K.; Gulhane, Rajesh; Shivani: Bismuth Oxide Perchlorate as a Highly Efficient Catalyst for Heteroatom Acylation Under Solvent-Free Conditions
https://www.thieme-connect.de/bilder/synlett/200312/d179_ga
1809
Ito, Katsuji; Akashi, Suemi; Saito, Bunnai; Katsuki, Tsutomu: Asymmetric Intramolecular Allylic Amination: Straightforward Approach to Chiral C1-Substituted Tetrahydroisoquinolines
https://www.thieme-connect.de/bilder/synlett/200312/u107_ga
1813
Berkenbusch, Thilo; Brückner, Reinhard: Concise Synthesis of Optically Pure syn-1,3-Diols by Stereoselective Desymmetrization of a Divinylcarbinol
https://www.thieme-connect.de/bilder/synlett/200312/g144_ga
1817
Zhang, Dong-hui; Zhou, Wei-shan: Synthetic Studies Towards Phorboxazole B: Stereoselective Synthesis of the C3-C19 Bis-oxane Oxazole Fragment
https://www.thieme-connect.de/bilder/synlett/200312/u137_ga
1822
Maes, Bert U. W.; Loones, Kristof T. J.; Lemière, Guy L. F.; Dommisse, Roger A.: The First Rapid Palladium-Catalyzed Aminations of (Azahetero)aryl Chlorides under Temperature-Controlled Microwave Heating
https://www.thieme-connect.de/bilder/synlett/200312/g148_ga
1826
Radics, Gábor; Koksch, Beate; El-Kousy, Salah M.; Spengler, Jan; Burger, Klaus: l-α-Methylhomoisoserine: A New Versatile Building Block for Peptide and Depsipeptide Modification
https://www.thieme-connect.de/bilder/synlett/200312/g141_ga
1830
Müller, Paul; Ghanem, Ashraf: Asymmetric Cyclopropanation of Olefins with an in situ Generated Phenyliodonium Ylide
https://www.thieme-connect.de/bilder/synlett/200312/g165_ga
1834
Boucard, Valérie; Larrieu, Karen; Lubin-Germain, Nadège; Uziel, Jacques; Augé, Jacques: C-Glycosylated Phenylalanine Synthesis by Palladium-Catalyzed Cross-Coupling Reactions
https://www.thieme-connect.de/bilder/synlett/200312/g109_ga
1838
Kim, Su Jeong; Bang, Eun-Kyoung; Kim, Byeang Hyean: Synthesis of Novel Phosphoramidite Building Blocks from Pentaerythritol
https://www.thieme-connect.de/bilder/synlett/200312/u135_ga
1841
Ballini, Roberto; Fiorini, Dennis; Palmieri, Alessandro: Highly Convenient, One-Pot Synthesis of Nitriles from Aldehydes Using the NH2OH·HCl/NaI/MeCN System
https://www.thieme-connect.de/bilder/synlett/200312/d140_ga
1844
El Kaïm, Laurent; Gautier, Laurent; Grimaud, Laurence; Michaut, Valerie: New Insight into the Azaenamine Behaviour of N-Arylhydrazones: First Aldol and Improved Mannich Reactions with Unactivated Aldehydes
https://www.thieme-connect.de/bilder/synlett/200312/d134_ga
1847
Martínez-Palou, Rafael; de Paz, Gerardo; Marín-Cruz, Jesús; Zepeda, Luis Gerardo: Synthesis of Long Chain 2-Alkyl-1-(2-hydroxyethyl)-2-imidazolines under Microwave in Solvent-Free Conditions
https://www.thieme-connect.de/bilder/synlett/200312/s041_ga
1850
Koike, Tooru; Mori, Atsunori: Palladium-Catalyzed Cross-Coupling Reaction of Silicone with Aryl Chlorides
https://www.thieme-connect.de/bilder/synlett/200312/u124_ga
1853
Atkinson, Sov; Meredith, Paul: Synthesis of Acetoxy Stabilised Indolequinones as Precursors to Model Eumelanin Polymers
https://www.thieme-connect.de/bilder/synlett/200312/d100_ga
1856
Viseux, E. M. E.; Parsons, P. J.; Pavey, J. B. J.; Carter, C. M.; Pinto, I.: Model Studies Towards the Total Synthesis of the Anticancer Agent Roseophili­n
https://www.thieme-connect.de/bilder/synlett/200312/d066_ga
1859
van Otterlo, Willem A. L.; Pathak, Rakhi; de Koning, Charles B.: Ruthenium-Mediated Isomerization and Ring-Closing Metathesis: Versatile Syntheses of 6-, 7- and 8-Membered Benzo-Fused Heterocycles
https://www.thieme-connect.de/bilder/synlett/200312/d159_ga
1862
Stanetty, Peter; Schnürch, Michael; Mihovilovic, Marko D.: Synthesis of Pyridinyl-Pyrimidines via Pd-Catalyzed Cross-Coupling Reactions: A Comparison of Classical Thermal and Microwave Assisted Reaction Conditions
https://www.thieme-connect.de/bilder/synlett/200312/d194_ga
1865
Tamai, Tetsuo; Asano, Shingo; Totani, Kiichiro; Takao, Ken-ichi; Tadano, Kin-ichi: Highly Stereoselective [3+2] Cycloadditions of Nitrile Oxides to Methyl 4-O-Acryloyl-6-deoxy-2,3-O-(t-butyldimethylsilyl)-α-d-glucopyranoside
https://www.thieme-connect.de/bilder/synlett/200312/u123_ga
1868
Tashiro, Aya; Mitsuishi, Akimasa; Irie, Ryo; Katsuki, Tsutomu: (NO)Ru(salen)-Catalyzed Aerobic Oxidation of o-Hydroxybenzyl Alcohol Derivatives­
https://www.thieme-connect.de/bilder/synlett/200312/u129_ga
1871
Cämmerer, Simon S.; Viciu, Mihai S.; Stevens, Edwin D.; Nolan, Steven P.: Use of (NHC)Pd(η3-allyl)Cl (NHC = N-Heterocyclic Carbene) in a Palladium-mediated Approach to Cryptocarya Alkaloids
https://www.thieme-connect.de/bilder/synlett/200312/s065_ga
1874
Maerten, Eddy; Hassouna, Fatima; Couve-Bonnaire, Samuel; Mortreux, André; Carpentier, Jean-François; Castanet, Yves: Direct Synthesis of Benzoylpyridines from Chloropyridines via a Palladium-Carbene Catalyzed Carbonylative Suzuki Cross-Coupling Reaction
https://www.thieme-connect.de/bilder/synlett/200312/g138_ga
1877
Zolfigol, Mohammad Ali; Mohammadpoor-Baltork, Iraj; Mirjalili, Bi Bi Fatemeh; Bamoniri, Abdolhamid: Silica Sulfuric Acid: An Efficient Catalyst for the Direct Conversion of Primary and Secondary Trimethylsilyl Ethers to their Corresponding Ethers under Mild and Heterogeneous Conditions
https://www.thieme-connect.de/bilder/synlett/200312/g116_ga
1880
Zeni, Gilson; Stracke, Marcelo Paulo; Lissner, Elizeo; Braga, Antonio Luiz: A Convenient Preparation of Chalcogenoenynes from β-Bromovinyl Ketene Chalcogenoacetals
https://www.thieme-connect.de/bilder/synlett/200312/s154_ga
1883
Motoyama, Yukihiro; Nishiyama, Hisao: Bis(oxazolinyl)phenylrhodium(III) Aqua Complex: Efficiency in Enantioselective Addition of Methallyltributyltin to Aldehydes under Aerobic Conditions
https://www.thieme-connect.de/bilder/synlett/200312/u148_ga
1886
Kalogerakis, Aris; Groth, Ulrich: Total Synthesis of the Angucylinone Antibiotic (+)-Rubiginone B2
https://www.thieme-connect.de/bilder/synlett/200312/g151_ga
1889
Pisaneschi, Federica; Cordero, Franca M.; Brandi, Alberto: Resin Linked Dipolarophiles to Mask Nitrones
https://www.thieme-connect.de/bilder/synlett/200312/g128_ga
1892
Korn, Tobias J.; Cahiez, Gérard; Knochel, Paul: New Cobalt-Catalyzed Cross-Coupling Reactions of Heterocyclic Chlorides with Aryl and Heteroaryl Magnesium Halides
https://www.thieme-connect.de/bilder/synlett/200312/g160_ga
1895
Alexander, Varughese M.; Khandekar, Amit C.; Samant, Shriniwas D.: Solvent-Free Iodination of Arenes at Room Temperature
https://www.thieme-connect.de/bilder/synlett/200312/g140_ga
1898
Maguire, Naomi E.; McLaren, Andrew B.; Sweeney, J. B.: Asymmetric Synthesis of Arylalanines via Asymmetric aza-Darzens (ADZ) Reaction
https://www.thieme-connect.de/bilder/synlett/200312/g152_ga

cluster

1901
Martin, Harry J.; List, Benjamin: Mining Sequence Space for Asymmetric Aminocatalysis: N-Terminal Prolyl-Peptides Efficiently Catalyze Enantioselective Aldol and Michael Reactions
https://www.thieme-connect.de/bilder/synlett/200312/y001_ga
1903
Pojarliev, Peter; Biller, William T.; Martin, Harry J.; List, Benjamin: Highly Enantioselective Synthesis of 1,2-Amino Alcohol Derivatives via Proline-Catalyzed Mannich Reaction
https://www.thieme-connect.de/bilder/synlett/200312/y002_ga
1906
Chowdari, Naidu S.; Ramachary, D. B.; Barbas III, Carlos F.: Organocatalysis in Ionic Liquids: Highly Efficient l-Proline-Catalyzed Direct Asymmetric Mannich Reactions Involving Ketone and Aldehyde Nucleophiles
https://www.thieme-connect.de/bilder/synlett/200312/y004_ga
1910
Ramachary, D. B.; Chowdari, Naidu S.; Barbas III, Carlos F.: The First Organocatalytic Hetero-Domino Knoevenagel-Diels-Alder-Epimerization Reactions: Diastereoselective Synthesis of Highly Substituted Spiro[cyclohexane-1,2′-indan]-1′,3′,4-triones
https://www.thieme-connect.de/bilder/synlett/200312/y005_ga
1915
Bøgevig, Anders; Poulsen, Thomas B.; Zhuang, Wei; Jørgensen, Karl Anker: Formation of Optically Active Functionalized β-Hydroxy Nitrones Using a Proline Catalyzed Aldol Reaction of Aldehydes with Carbonyl Compounds and Hydroxylamines
https://www.thieme-connect.de/bilder/synlett/200312/y003_ga
1919
Wenzel, Anna G.; Lalonde, Mathieu P.; Jacobsen, Eric N.: Divergent Stereoinduction Mechanisms in Urea-Catalyzed Additions to Imines
https://www.thieme-connect.de/bilder/synlett/200312/y009_ga
1923
Griswold, Keith S.; Horstmann, Thomas E.; Miller, Scott J.: Acyl Sulfonamide Catalysts for Glycosylation Reactions with Trichloroacetimidate Donors
https://www.thieme-connect.de/bilder/synlett/200312/y007_ga
1927
Hang, Jianfeng; Deng, Li: Dynamic Kinetic Resolution for Asymmetric Synthesis of α-Alkyl Amino Acids via Dual-Function Catalysis of Modified Cinchona Alkaloids
https://www.thieme-connect.de/bilder/synlett/200312/y010_ga
1931
Ooi, Takashi; Kubota, Yasushi; Maruoka, Keiji: A New N-Spiro C2-Symmetric Chiral Quaternary Ammonium Bromide Consisting of 4,6-Disubstituted Biphenyl Subunit as an Efficient Chiral Phase-Transfer Catalyst
https://www.thieme-connect.de/bilder/synlett/200312/y006_ga
1934
Kerr, Mark S.; Rovis, Tomislav: Effect of the Michael Acceptor in the Asymmetric Intramolecular Stetter Reaction
https://www.thieme-connect.de/bilder/synlett/200312/y008_ga
1937
Shah, Meha H.; France, Stefan; Lectka, Thomas: Bicarbonate Salts as Cost-Effective Bases for the Synthesis of Ketenes and Their Synthetic Equivalents Applied to the Asymmetric Synthesis of β-Lactams
https://www.thieme-connect.de/bilder/synlett/200312/s072_ga

spotlight

1940
Goundry, William R. F.: Trimethylsilyl Trifluoromethanesulfonate (TMSOTf)
1942
Pasupathy, K.: Magnesium/Methanol