DOI: 10.1055/s-00000083

Synlett

Issue 02 · Volume 2009 · January 2009 DOI: 10.1055/s-002-15168

account

159
Ochiai, Masahito: Hypervalent Aryl-, Alkynyl-, and Alkenyl-λ³-bromanes
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174
Brodmann, Tobias; Lorenz, Michael; Schäckel, Romy; Simsek, Serkan; Kalesse, Markus: Highly Stereoselective Aldol Reactions in the Total Syntheses of Complex Natural Products
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letter

193
Richter, Heinrich; Schwertfeger, Hartmut; Schreiner, Peter R.; Fröhlich, Roland; Glorius, Frank: Thieme Chemistry Journal Awardees - Where are They Now? Synthesis of Diamantane-Derived N-Heterocyclic Carbenes and Applications in Catalysis
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198
Fukuhara, Tadahito; Hara, Shoji: Desulfurizing Difluorination Reaction of Benzyl Sulfides Using IF5
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201
Fatunsin, Olumide; Shkoor, Mohanad; Riahi, Abdolmajid; Dede, Rüdiger; Reinke, Helmut; Langer, Peter: First Synthesis of Functionalized Benzonitriles by Formal [3+3] Cyclocondensations of 1,3-Bis(silyloxy)buta-1,3-dienes
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205
Filali, Emane; Lloyd-Jones, Guy C.; Sale, David A.: Cleavage of tert-Butyl Benzoates with NaH in DMF: Comments on the ­Mechanism and a Simple and Safe Alternative Procedure
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209
Radha Krishna, Palakodety; Srinivas Reddy, P.: Stereoselective Total Synthesis of (+)-Valienamine and (+)-4-epi-Valienamine via a Ring-Closing Enyne Metathesis Protocol
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213
Sonawane, Ravindra P.; Joolakanti, Shyamsunder R.; Arseniyadis, Stellios; Cossy, Janine: Asymmetric Pentenylation of Aldehydes: A New Benchmark for the Preparation of Ethyl-Substituted Homoallylic Alcohol
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217
Muller, Thierry; Heuschling, Paul; Luu, Bang: Regio- and Chemoselective One-Step 3-O-Alkylenation of Unprotected Ascorbic Acid Using ω-Iodoalkanols
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221
Libnow, Stefanie; Hein, Martin; Langer, Peter: The First N-Glycosylated Indoxyls and Their Application to the Synthesis of Indirubin-N-glycosides (Purple Sugars)
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225
Lavén, Gaston; Stawinski, Jacek: Palladium(0)-Catalyzed Benzylation of H-Phosphonate Diesters: An Efficient Entry to Benzylphosphonates
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229
Terzidis, Michael A.; Tsoleridis, Constantinos A.; Stephanidou-Stephanatou, Julia: Methylisoquinoline-Based Three-Component Condensation Reactions Involving Chromone-3-carboxaldehydes: One-Pot Synthesis of a New Class of Chromenopyridoisoquinolines
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233
McErlean, Christopher S. P.; Willis, Anthony C.: Application of an Intramolecular Stetter Reaction to Access trans,syn,trans-Fused Pyrans
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Supporting Information
237
Zhang, Yu; Gerasyuto, Aleksey I.; Long, Quincy A.; Hsung, Richard P.: A General Approach to the Quinolizidine Alkaloids via an Intramolecular Aza-[3+3] Annulation: Synthesis of (±)-2-Deoxylasubine II
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Supporting Information
241
Shibatomi, Kazutaka; Muto, Tsubasa; Sumikawa, Yusuke; Narayama, Akira; Iwasa, Seiji: Development of a New Chiral Spiro Oxazolinylpyridine Ligand (Spymox) for Asymmetric Catalysis
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245
Sakurai, Hidehiro; Kamiya, Ikuyo; Kitahara, Hiroaki; Tsunoyama, Hironori; Tsukuda, Tatsuya: Aerobic Oxygenation of Benzylic Ketones Promoted by a Gold Nanocluster Catalyst
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249
Lee, Hee-Yoon; Sampath, Vasu; Yoon, Yeokwon: A Facile Total Synthesis of All Stereoisomers of Tarchonanthuslactone and Euscapholide from Chiral Epichlorohydrin
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253
Inagaki, Tomohiko; Yamada, Yoko; Phong, Le Thanh; Furuta, Akihiro; Ito, Jun-ichi; Nishiyama, Hisao: Catalytic Hydrosilylation of Carbonyl Compounds with Zinc(II) Acetate: Asymmetric Induction Collaborated with N2S2 Ligands
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257
Christie, Steven D. R.; Cummins, Jaime; Elsegood, Mark R. J.; Dawson, Graham: Formation of Polysubstituted Tetrahydrofurans on an Iron Tricarbonyl η5-Pentadienyl Template
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260
Nikulnikov, Mikhail; Tsirulnikov, Sergey; Kysil, Volodymyr; Ivachtchenko, Alexandre; Krasavin, Mikhail: tert-Butyl Isocyanide as a Convertible Reagent in Ugi Reaction: Microwave-Assisted Preparation of 5,6-Dihydropyrazolo[1,5-a]pyrazine-4,7-diones
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263
Claveau, Elise; Gillaizeau, Isabelle; Coudert, Gérard: An Efficient Approach to Original Substituted 2-Arylidene-2H-[1,4]-oxazin-3(4H)-ones via a Tandem Intramolecular P(O→C) Migration/Horner-­Wadsworth-Emmons Olefination Sequence
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268
Ballini, Roberto; Bosica, Giovanna; Palmieri, Alessandro; Bakhtiari, Khadijeh: Solvent-Free, anti-Michael Addition of Active Methylene Derivatives to β-Nitroacrylates: Eco-Friendly, Chemoselective Synthesis of Polyfunctionalized Nitroalkanes
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271
Semeniuchenko, Volodymyr; Khilya, Volodymyr; Groth, Ulrich: Nucleophilic Homogeneous Hydrogenation by Iridium Complexes
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276
Dal Zotto, Christophe; Virieux, David; Campagne, Jean-Marc: FeCl3-Catalyzed Reduction of Ketones and Aldehydes to Alkane Compounds
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279
Mateos-Caro, Julia; Robin, Yves; Levacher, Vincent; Marsais, Francis: Controlled Ring Opening of N-Sulfinyl- and N-Silyl-N-carboxyanhydrides (NCA): One-Pot Synthesis of Dipeptides and Unsymmetrical Peptidyl Ureas from Unprotected NCA
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284
Cikotiene, Inga; Morkunas, Marius: The First and Efficient Synthesis of 7-Aryl-6-methoxycarbonylquinazolines via Unexpected Reaction of 6-Arylethynylpyrimidine-5-carbaldehydes and Methyl Mercaptoacetate
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287
Busacca, Carl A.; Bartholomeyzik, Teresa; Cheekoori, Sreedhar; Raju, Ravinder; Eriksson, Magnus; Kapadia, Suresh; Saha, Anjan; Zeng, Xingzhong; Senanayake, Chris H.: Reduction of Phosphinites, Phosphinates, and Related Species with DIBAL-H
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292
Taj, Rafiq A.; Abhayawardhana, Anusha; Green, James R.: Cyclohepta[de]naphthalenes and the Rearranged Abietane Framework of Microstegiol via Nicholas Reaction Chemistry
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297
Jiang, Li-Jiao; Lan, Hong-Qiao; Zheng, Jian-Feng; Ye, Jian-Liang; Huang, Pei-Qiang: A Flexible Approach to Methyl (5S)-5-Alkyltetramate Derivatives
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Supporting Information
302
Neochoritis, Constantinos; Stephanidou-Stephanatou, Julia; Tsoleridis, Constantinos A.: Heterocyclizations via TosMIC-Based Multicomponent Reactions: A New Approach to One-Pot Facile Synthesis of Substituted Quinoxaline Derivatives
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306
Faragalla, Jane; Heaton, Andrew; Griffith, Renate; Bremner, John B.: A Facile Approach to 2-Substituted Isoflav-3-enes via Isoflavylium Salts
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310
Bajracharya, Gan B.; Koranne, Priti S.; Tsujihara, Tetsuya; Takizawa, Shinobu; Onitsuka, Kiyotaka; Sasai, Hiroaki: Dicationic Palladium(II)-Spiro bis(isoxazoline) Complex for Highly Enantioselective Isotactic Copolymerization of CO with Styrene Derivatives
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Supporting Information
315
Gao, Meng; Cao, Liping; Wang, Zihua; Sun, Jingjing; She, Nengfang; Wu, Anxin: Synthesis of Novel Molecular Clips via Click Chemistry Based on Diethoxy carbonyl Glycoluril
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Supporting Information

new tools

320
Catalytic Enantioselective α-Arylation of Carbonyl Compounds
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spotlight

328
Santra, Soumava: Burgess Reagent: From Oblivion to Renaissance in Organic Synthesis
330
Lü, Hong-Yan: Phenyltrimethylammonium Tribromide: A Versatile Reagent in Organic Synthesis

addenda and errata

332
Synthesis of Chiral Carbohydrate Ionic Liquids