Synfacts
Issue 10 · October 2011
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A89
SYNFORM
ISSUE 2011/10
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Synthesis of Natural Products and Potential Drugs
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1039
Synthesis of (+)-Liphagal
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1040
Synthesis of Aliskiren
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1041
Synthesis of a 5HT
7
/5HT
2
Dual Antagonist
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1042
Synthesis of (-)-Kumausallene
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1043
Synthesis of (+)-Omphadiol
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1044
Synthesis of Glucokinase Activator MK-0941
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1045
Synthesis of (-)-Isatisine A
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1046
Synthesis of Toll-like Receptor Agonist PF-4171455
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1047
Synthesis of a PARP Inhibitor
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1048
Synthesis of (-)-Neodysiherbaine A
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1049
Synthesis of the Loline Alkaloids
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1050
Synthesis of (-)-Zampanolide
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Synthesis of Heterocycles
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1051
Synthesis of 2-Aminoepoxides from Aminohalohydrins Using KF on Celite
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1052
Pd-Catalyzed Synthesis of Quinazolin-4(3
H
)-ones from
N
-Aryl Amidines
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1053
Pd-Catalyzed Synthesis of 1,4-Dihydro-pyridines via a Multicomponent Reaction
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1054
A Convenient 1,3-Dipolar Cycloaddition Approach to Pyridylpyrroles
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1055
Oxazinoisoquinoline Synthesis via the Unusual Reactivity of Aminomethylnaphthols
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1056
Pericyclic Approach to Synthesis of Substituted Pyrazoles
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1057
Gold-Catalyzed Heteroannulation Route to Indolin-3-ones and Indoles
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1058
1-Benzoxepines from 2-Acylmethoxyaryl Boronic Acids and Allenoates
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1059
Intramolecular Ullmann Cross-Coupling Route to Fused Pyridoquinazolinones
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1060
Sulfonylpyrazoles via Base-Mediated Reaction of Diazosulfone with Nitroalkenes
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1061
One-Pot Enantioselective Michael-Aldol Approach to Imidazole Derivatives
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1062
Synthesis of Enantiopure Piperidines via an Aziridinium Ring Expansion Reaction
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1063
Palladium-Catalyzed C-H Activation Induced Enantioselective Route to Fused Indolines
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1064
Cu-Catalyzed Oxidative Synthesis of Tetrahydroquinolines from
N
-Methylanilines
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1065
Ni-Catalyzed Cycloaddition Approach to Coumarins by C-C σ-Bond Cleavage
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Synthesis of Materials and Unnatural Products
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1067
Highly Fluorescent Dyes, Never Mind the Heavy Atoms
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1068
Highly Charged Oxidized Tetrathiafulvalene Oligomers
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1069
Multicomponent Polymerizations: It’s All about the Solvent
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1070
New Additions to the Triptycene Family
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1071
Fluorescent Triazapentalenes
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1072
Synthesis of a ‘Fused’ BN Indole
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1073
Palladium Catalysis for Extended PAHs
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1074
One-Pot Synthesis of Unusual 15-Membered Polyether Macrocycles
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1075
Dibenzotetrathienocoronenes and Hexabenzocoronene in Three Steps
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1076
Two’s Company, Six is a Crowded Triptycene
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1077
Photodimerization of Arenediynes
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1078
Nine in a Row: Taming the Acenes
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1079
Photochromism in Reverse
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z1081
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1081
Rh(I)-Catalyzed Pauson-Khand Cycloaddition
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1082
Enantioselective Vanadium-Catalyzed Oxidation of 1,3-Dithianes
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1083
Purification of Alkene Stereoisomers through
Z
-Selective Ethenolysis
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1084
Asymmetric Dirhodium-Catalyzed Cyclopropenation of Terminal Alkynes
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1085
Asymmetric Hydrogenation of Heterocyclic Ketone-Derived Hydrazones
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1086
Iridium-Catalyzed Asymmetric Double Crotylation of 1,3-Diols
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1087
Asymmetric Decarboxylative Allylation of Oxindoles
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1088
Nickel-Catalyzed Tandem Isomerization-Mannich Reaction
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1089
Enantioselective Pd(II)-Catalyzed Aerobic Oxidative Amidation of Alkenes
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1090
Enantioselective
gem
-Chlorofluorination of Active Methylene Compounds
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1091
Nazarov Cyclizations of Dienyl Diketones Initiated by Conjugate Addition
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1092
Asymmetric Hydrogenation of Cyclic
N
-Alkyl Imines
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1093
Cu(II)-Catalyzed Synthesis of Substituted Tetrahydropyrans
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1094
Catalytic Enantioselective Synthesis of Tetrahydro-4-ones
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1095
Copper-Catalyzed Enantioselective Hydroboration
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1096
Rhodium-Catalyzed Trapping of Oxonium Ylides with Michael Acceptors
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1097
Effects of Salen Ligands in Ti-Catalyzed Cyanosilylation of Aldehydes
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1098
Enantioselective Allylic Substitutions with Hydroxamic Acid Derivatives
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1099
Dysprosium(III) Triflate Catalyzed Aza-Piancatelli Rearrangement
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1100
Cu-Catalyzed Asymmetric Propargylation of Ketones
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1101
Binary Acid System for Asymmetric Regioselective 1,2- and 1,4- Addition
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1102
Catalytic Asymmetric C-H Insertions of Rhodium(II) Azavinyl Carbenes
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1103
Asymmetric Transfer Hydrogenation of α,α-Disubstituted Ketones
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1104
Conjugate Addition Approach Towards Unnatural Amino Acid Derivatives
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1105
Chiral Diamine-Polyoxometalate (POM) Acid Catalyzed Aldol Reaction
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1106
N
,
N
′-Dioxide-Ni Complex Catalyzed Asymmetric Michael Addition
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1107
Iridium-Catalyzed Asymmetric Hydrogenation of Ketones
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1108
Asymmetric Allylic Alkylation of Diverse Nitrogen-Containing Heterocycles
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1109
Asymmetric Arylation of Aliphatic Aldimines
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Metal-Mediated Synthesis
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1111
Direct Suzuki-Miyaura Coupling of Phenol Derivatives via Mutual Activation
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1112
Cu-Mediated Trifluoromethylation of Benzyl Bromides
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1113
Pd-Catalyzed One-Pot Process to Yield 8-Arylquinolines
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1114
Ni-Catalyzed Cross-Coupling of Aryl Halides with Diphenylphosphine Oxide
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1115
Regioselective Oxidative Couplings of 3-Substituted Thiophenes
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1116
One-Pot
ortho
-Borylation and Subsequent Cross-Coupling-Reaction
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1117
Suzuki Coupling of an Aminomethyl Equivalent with (Hetero)Aryl Halides
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1118
Preparation and Reaction of Chiral Difluoroallylboronates
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1119
Pd-Catalyzed Synthesis of (Het)Ar-SCF
3
Compounds
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1120
Ni-Catalyzed Alcohol-Carbonyl Interconversions
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1121
Cu-Catalyzed Coupling Reaction to Yield Ynimides
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1122
Pd-Catalyzed Construction of 2,3-Diaryl 1,4-Diketones
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1123
Pd-Catalyzed Anti-Markovnikov Hydroalkylation of Allylic Amines
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1124
Synthesis of Polyfluoro-2,2-diarylethanes
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Organo- and Biocatalysis
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1125
Collective, Organocatalytic Syntheses of Natural Products: Strychnos Alkaloids
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1126
Asymmetric Mannich Reaction of a HWE Reagent to Afford MBH-Type Products
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1127
Synthesis of α-Amino Acid Derivatives by Biomimetic Transamination
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1128
Organocatalytic Enantioselective Fluorocyclizations
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1129
Metal-Free Intra- and Intermolecular Oxidative C-N Bond Formation
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1130
Asymmetric Olefin Isomerization of Butenolides
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1131
Enantioselective Protonation of Enol Silanes by Protonated Chiral Sulfinamides
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1132
Brønsted Acid Catalysis: Friedel-Crafts Alkylation with Chiral Disulfonimides
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1133
Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Ketimines
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1134
exo
-Selective Diels-Alder Reaction of 2,4-Dienals and Nitroalkenes
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Polymer-Supported Synthesis
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1135
Polystyrene-Supported Iodosylbenzene as an Oxidizing Reagent
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1136
Asymmetric Aldol Reactions in Brine with Fluorous Organocatalysts
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1137
Cycloaddition of Tetramethyldisiloxane to Alkynes with [Au]/TiO
2
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1138
Synthesis of 2-Aminobenzothiazoles with a Polymeric Phen-Cu(I) Complex
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1139
Cross-Coupling Using Mesoporous Pd-MCM-48
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1140
Synthesis of Propargylamines with In
2
O
3
Nanoparticles
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1141
Arylation of Heterocycles with a CuO Nanospindle
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1142
Pd Nanoparticles in the Metal-Organic Framework MIL-101
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1143
Asymmetric Epoxidation with a Chiral Metal-Organic Framework
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1144
Asymmetric Henry Reaction with MCM-41-Supported Cu-Salen Complex
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1145
Oxidation of Olefins and Alcohols with Pt@Fe
2
O
3
Nanowires
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1146
Hosomi-Sakurai Reaction with Silicomolybdic Acid
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1147
Solid-Phase Synthesis of Tetrahydrobenzo-diazepine Derivatives
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1148
An Organosilica-Supported Pd Catalyst
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