Synfacts

Issue 00 · July 2005

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Synthesis of Natural Products and Potential Drugs
0001
Catalytic Asymmetric Synthesis of Apple Leafminer Pheromones FREE ACCESS

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0002
A Synthesis of Virantmycin via Enzyme-Mediated Diester Desymmetrization FREE ACCESS

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0003
Total Synthesis of (-)-Colombiasin and
(-)-Elisapterosin B FREE ACCESS

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0004
Total Synthesis of (+)-Leucascandrolide A FREE ACCESS

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0005
Total Synthesis of Crambescidins 359 and 431 FREE ACCESS

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0006
Total Synthesis of (-)-Aurisides A and B FREE ACCESS

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0007
Total Synthesis of (-)-Minovine FREE ACCESS

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0008
Total Synthesis of (-)-SNF4435 C and
(+)-SNF4435 D FREE ACCESS

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0009
Total Synthesis of Aureothin and N-Acetylaureothamine FREE ACCESS

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0010
Asymmetric Zn Aldol Additions: Asymmetric Synthesis of Fostriecin FREE ACCESS

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0011
Total Syntheses of Benzastatin E and Virantmycin FREE ACCESS

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0012
Total Synthesis of (-)-Agelastatin FREE ACCESS

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0013
Total Synthesis of Caprazol FREE ACCESS

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0014
Total Synthesis of (+)-Myristinin A, a Potent DNA-Damaging Agent FREE ACCESS

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0015
Asymmetric Synthesis of L-869,298, a Potent PDE4 Inhibitor FREE ACCESS

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Synthesis of Heterocycles
0017
Cycloaddition Chemistry of 2-Vinyl-Substi-tuted Indoles and Related Heteroaromatics FREE ACCESS

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0018
Synthesis of 1-Phosphabarrelene Phosphine Sulfide Substituted Palladium(II) Complexes FREE ACCESS

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0019
Synthesis of Diversely Functionalized Hexa-hydropyrrolo[2,3-b]indoles FREE ACCESS

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0020
Total Synthesis of the Marine Natural Product rac-Dibromophakellstatin FREE ACCESS

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0021
Radical-Mediated Synthesis of Sesquiterpene Lactones FREE ACCESS

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0022
Catalytic C-H Functionalization Driven by CO as a Stoichiometric Reductant - Application to Carbazole Synthesis FREE ACCESS

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0023
Poly(thiaheterohelicene): A Stiff Conjugated Helical Polymer Comprised of Fused Benzothiophene Rings FREE ACCESS

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0024
Generation and Aromaticity of 2-Silaimidazo-lium Ion, a New π-Conjugated Silylium Ion FREE ACCESS

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0025
Directed Palladation: Fine Tuning Permits the Catalytic 2-Alkenylation of Indols FREE ACCESS

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0026
Coupling of 1-Alkyl-2-(bromomethyl)aziri-dines with Lithium Dialkylcuprates towards 1,2-Dialkylaziridines FREE ACCESS

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0027
Superacid-Promoted Reactions of Pyrazole-carboxaldehydes and the Role of Dicationic Electrophiles FREE ACCESS

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0028
Bis-acetylenic Ketones for the Synthesis of 1,2,4-Triazepine and Oxatriazaindenone Cores FREE ACCESS

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0029
An Efficient Synthesis of Bibutenolides from 2,3-Allenoic Acids FREE ACCESS

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0030
Ru-Catalyzed ortho-Selective Direct Cross-Coupling Reaction of 2-Aryloxazolines and 2-Arylimidazolines FREE ACCESS

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0031
A Stable P-Heterocyclic Carbene FREE ACCESS

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Synthesis of Materials and Unnatural Products
0033
Preparation of Hangman Salophens FREE ACCESS

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0034
Preparation of Star-Shaped Linear Nanosized polycyclic aromatics FREE ACCESS

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
0035
Ir-Catalyzed Allylic Amination and Etherification FREE ACCESS

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0036
Enantioselective Friedel-Crafts Alkylations of Pyrroles and Indoles via α′-Hydroxyenones FREE ACCESS

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0037
Immobilized Ir-(P-Phos) Complex for Enantioselective Hydrogenation of Quinolines FREE ACCESS

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0038
Base-Free Asymmetric Transfer Hydrogenation of Aromatic Ketones FREE ACCESS

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0039
‘True’ Chirality Transfer from Silicon to Carbon FREE ACCESS

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0040
Enantioselective Protonation of Silyl Enolates Catalyzed by a Binap-AgF Complex FREE ACCESS

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0041
Organosilanols as Catalysts in Asymmetric Aryl Transfer Reactions FREE ACCESS

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0042
‘One-Pot’ Zr-Catalyzed Asymmetric Carboalumination-Pd Cross-Coupling FREE ACCESS

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0043
Enantioselective [3+2] Cycloaddition of Allenylsilanes with α-Imino Esters FREE ACCESS

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0044
Molecular Weight Induced Enantioreversal in Sharpless Asymmetric Epoxidation FREE ACCESS

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0045
Exo-Selective Enantioselective Nitrone Cycloaddition FREE ACCESS

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0046
Selective 1,3-Isomerization of Allylic Alcohols via Rhenium Oxo Catalysis FREE ACCESS

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0047
Hydroxylamines as Oxygen-Based Nucleo-philes in Allylic Substitution Reaction FREE ACCESS

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0048
Enantioselective Friedel-Crafts Alkylations by Strained Chiral Silacycle FREE ACCESS

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0049
Enantioselective Enol Lactone Synthesis under Double Catalytic Conditions FREE ACCESS

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0050
Enantioselective Synthesis of anti-Propionate Aldols via Radical Addition FREE ACCESS

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0051
exo-Selective Catalysts for 1,3-Dipolar Nitrone Cycloaddition FREE ACCESS

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0052
Pd-Catalyzed Diastereoselective Iodination of Unactivated C-H Bonds FREE ACCESS

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0053
Catalytic Asymmetric Synthesis of Chiral Allylic Esters FREE ACCESS

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0054
Asymmetric Allylation of Aldehydes Catalyzed by a Chiral Indium(III)-BINOL Complex FREE ACCESS

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0055
Diastereoselective Ring-Closing Metathesis to Build a Quaternary Carbon Center FREE ACCESS

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0056
Enantioselective Diethylzinc Addition to Alde-hydes Catalyzed by Dialkylaminoisoborneols FREE ACCESS

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0057
CuF₂-Catalyzed Enantioselective Synthesis of Allylic Alcohols and Diarylmethanols FREE ACCESS

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0058
Direct Dinuclear Zinc Aldol Addition FREE ACCESS

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0059
Chiral Ferrocenyl Phosphine-Triazines as Ligands for Asymmetric Allylic Substitution FREE ACCESS

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0060
Scandium(III) Triflate-Catalyzed Stereoselec-tive Synthesis of Tetrahydropyran-4-ones FREE ACCESS

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0061
Pd-Catalyzed Allylic Alkylation of Ketones FREE ACCESS

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Metal-Mediated Synthesis
0063
New Synthesis of Heterocycles via Azatitanacyclopentadiene Intermediates FREE ACCESS

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0064
Carboxylation and Esterification of Functionalized Arylcopper Reagents FREE ACCESS

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0065
Modular Catalysts for the Enantioselective Allylation of Aldehydes FREE ACCESS

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0066
Diastereoselective Rh-Catalyzed Addition of Arylboron Compounds to Sulfinimines FREE ACCESS

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0067
Catalytic Asymmetric Addition of Ethoxyvinyl-zinc to Aldehydes: Two-Carbon Homologation FREE ACCESS

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0068
Iron-Catalyzed Homo-Coupling of Arylmagnesium Reagents FREE ACCESS

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0069
Germanium(II)-Mediated Cross-Aldol Reac-tion between Aldehydes and Bromoaldehydes FREE ACCESS

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0070
Hydroboration with Pyridine Borane FREE ACCESS

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0071
Ni-Catalyzed Alkylative Dimerization of Vinyl Grignard Reagents Using Alkyl Fluorides FREE ACCESS

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0072
Novel Asymmetric Synthesis of Homopropar-gylic Alcohols via Allenylboration FREE ACCESS

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0073
A General Process for Synthesis of Enantiopure Sulfinates and Sulfoxides FREE ACCESS

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0074
Indium-Mediated Asymmetric Allylation of Aldimines in Methanol FREE ACCESS

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Organo- and Biocatalysis
0075
Enantioselective Fluoronation With a Simple Organic Catalyst FREE ACCESS

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0076
Asymmetric Organocatalytic Epoxidation of α,β-Unsaturated Aldehydes FREE ACCESS

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Polymer-Supported Synthesis
0077
Stereocontrolled SPOS of an Indoline-Alkaloid-like Library FREE ACCESS

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0078
Cooperative Catalysis by General Acid and Base Bifunctionalized Mesoporous Silica Nanospheres FREE ACCESS

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0079
Polymer-Supported Organotin Reagents for Regioselective Halogenation of Aromatic Amines FREE ACCESS

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0080
A Polymeric FeCl₃ Catalyst for Deprotection of Acetonides FREE ACCESS

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0081
Solid-Phase Synthesis of Photochromic Spiropyrans FREE ACCESS

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0082
Bulky Diarylammonium Arenesulfonates as Selective Esterification Catalysts FREE ACCESS

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0083
A Poly(ethylene glycol)-Supported Chiral Auxiliary for Asymmetric Michael Reaction FREE ACCESS

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0084
Evans’ Asymmetric Alkylation on Solid Supports FREE ACCESS

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0085
Asymmetric PTC for Preparation of a-Amino Acids FREE ACCESS

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0086
A Rapid Microwave-Assisted Esterification Utilizing the Mukaiyama Supported Reagent FREE ACCESS

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0087
Polymeric DBU for Preparation of Glycosyl Trichloroacetimidates FREE ACCESS

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0088
CO₂ Fixation with a Polymer-Supported Nanogold Catalyst FREE ACCESS

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0089
Polymer-Supported Chiral Lewis Base Catalysts FREE ACCESS

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