Synfacts

Issue 03 · December 2005

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Synthesis of Natural Products and Potential Drugs
0271
Synthesis of Lucilactaene

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0272
Synthesis of RK-397

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0273
Synthesis of Salinosporamide A

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0274
Synthesis of Cavicularin and Riccardin C

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0275
Synthesis of Latrunculin A

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0276
Synthesis of Brevetoxin B

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0277
Synthesis of Mycalamide A

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0278
Synthesis of (+)-Dactylolide

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0279
Synthesis of (R)-Tolterodine

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0280
Synthesis of P-3622

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0281
Synthesis of an NK₁ Receptor Antagonist

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0282
Biomimetic Synthesis of Elysiapyrones A and B

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0283
Synthesis of (+)-Julifloridine

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0284
Biomimetic Synthesis of Juliprosine and Juliprosopine

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0285
Synthesis of Castanospermine

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Synthesis of Heterocycles
0287
New Synthesis of Fischer Indole Hydrazone Intermediates

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0288
Enantioselective Diels-Alder Route to Isoquinuclidines

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0289
Regioselective Synthesis of 2-Substituted 3-Acylindoles

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0290
Synthesis of Bridged Bicyclic Lactones of Dihydroheteroaromatics

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0291
Stereoselective Iodine-Mediated Synthesis of Diazabicyclo[2.2.1]heptanes

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0292
Synthesis of Fluoropyrroles

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0293
Au(III)-Catalyzed Synthesis of Polysubstituted Halofurans

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0294
A Cascade Azide Formation, Cycloaddition and Michael Addition to a Quinolizidine

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0295
Synthesis of Bicyclic O- and N-Bridged Piperazines

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0296
[3+3] Cycloaddition Approach to the Synthesis of Substituted Pyrans and Oxapanes

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0297
[2+2+2] Cyclotrimerization to Benzofurans, Benzothiophenes and Isoindoles

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0298
Electrochemical Synthesis of Oxygenated Dihydrofurans

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0299
Negishi Cross Coupling Route to N-Unsubstituted α,α-Difluorohomophthalimides

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0300
Synthesis of Oxindole and β-Lactam Spiro-ethers

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0301
The Synthesis of an N-Heterocyclic Carbene-Stabilized Gold(I) Fluoride

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Synthesis of Materials and Unnatural Products
0303
Planar Chiral Cyclic Ether

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0304
Preparation of NCN Pincer Palladium Complexes via a Ligand Introduction Route

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
0305
Quinone Diels-Alder Reactions Catalyzed by a [(Schiff Base)Cr^III] Complex

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0306
Enantiopure α-Difluoromethyl Amines from N-(tert-Butylsulfinyl)aldimines

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0307
‘Open-Flask’ Enantioselective Reduction of Ketimines

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0308
Vinylideneruthenium-Catalyzed Homo and Cross Dimerization of Acetylenes

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0309
Diastereoselective Formation of Cyclopropanation from α,β-Epoxy Ketones

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0310
Allylic Transfer Reaction of Diene with Diboronyl Reagent and Aldehydes

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0311
Sp³ C-H Functionalization via a Lewis Acid-Catalyzed Redox Event

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0312
Total Synthesis of (-)-Colchicine via a Rh-Triggered Cycloaddition Cascade

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0313
Chiral Diene-Rhodium Complex Catalyzed 1,4-Addition of Arylboronic Acids

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0314
Diastereoselective Synthesis of Highly Substituted Cyclopentenones

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0315
4-(Dimethylamino)pyridine Analogue Bearing a Sulfoxide as Chiral Inducer

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0316
Asymmetric Ring Opening of meso-Epoxides in Water

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0317
Reductive Aldol Cyclizations: Synthesis of β-Hydroxylactones

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0318
Stereoselective Reduction of Dicarboxylic Esters using NaBH₄-InCl₃

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0319
Catalytic Prins Cyclization using In(OTf)₃ and Silyl Additives

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0320
Synthesis of Bicyclic Cyclohexadienes via Rh-Catalyzed Carbocyclization

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0321
Ti(IV)-Catalyzed Asymmetric Nitrone Cycloaddition

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0322
Gd(III)-Catalyzed Desymmetrization of Aziridines

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0323
MCR of Organoaluminium, Isoprene, Aldehydes and Amines

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0324
Kinetic Resolution of Dihydroxybiaryls via Asymmetric Transfer Vinylation

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0325
Diastereoselective Synthesis of 1,2,3,5-Tetrasubstituted Pyrrolidines

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0326
Enantioselective Aldol-Tishchenko Reaction

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Metal-Mediated Synthesis
0327
A Mild Deoxygenation of Alcohols by Trialkylboranes-Air via Xanthate Esters

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0328
New Powerful Reagents for Cyclopropanation of Alkenes

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0329
Iron-Catalyzed Cross-Coupling of Arylmagnesium Derivatives with Alkyl Halides

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0330
Enantio- and Diastereoselective Tandem Preparation of Cyclopropyl Alcohols

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0331
Stereoselective Reductive Coupling of Chiral Sulfinyl Imines with Aldehydes

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0332
Pd-Catalyzed Addition of Arylboronic Acids to Benzaldehydes

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0333
Enantioselective Arylation of Aldehydes with Triarylboranes-Ammonia

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0334
Stereoselective Cross-Coupling of 1,1-Diborylalkenes

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0335
A New Method for the Reduction of Secondary Phosphine Oxides

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0336
Nickel-Catalyzed Alkylation of Aldehydes with Trialkylboranes

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0337
Cu-Catalyzed Addition of Boronic Acids to Azodicarboxylates

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0338
Zinc-Carbenoids-Mediated Homologation of β-Keto Esters

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0339
Pd-Catalyzed Coupling of Propargylic Oxiranes with Arylboronic Acids

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0340
Vanadium-Catalyzed Pinacol Coupling of Benzaldehydes in Water

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Organo- and Biocatalysis
0341
Enantioselective Thiourea-Catalyzed Acyl-Mannich Reactions of Isoquinolines

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0342
Highly Enantioselective Allylic Amination by Cinchona Alkaloids

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0343
Hypervalent Organophosphorus Compounds as Organocatalysts

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0344
Highly Enantioselective Tandem Conjugate Thiol Addition-Amination Reaction

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0345
Proline-Catalyzed (S)-Oxybutynin Precursor Synthesis

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0346
A One-Pot Synthesis of Chiral Dihydro-1,2-oxazines

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0347
Organocatalytic Asymmetric Reductive Michael Cyclization of Enal Enones

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0348
Enantioselective α-Bromination of Aldehydes and Ketones with Simple Organic Catalysts

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0349
Enantioselective Organo-Cascade Catalysis of α,β-Unsaturated Aldehydes

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0350
Multidentate Hydrogen Donor Catalyzed Addition to Imines

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Polymer-Supported Synthesis
0351
Total Synthesis of TANDEM on Solid Phase

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0352
Enantioselective Synthesis of Linear Polypropionate Arrays

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0353
New Polymer-Supported Organosilicon Reagents

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0354
Synthesis of 1,4-Disubstituted-6-nitro-3,4-dihydro-1H-quinoline-2-ones

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0355
Facile Separation of Catalyst and Byproducts by Self-Encapsulation

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0356
DMAP-Mesoporous Silica Nanosphere as a Heterogeneous Nucleophilic Catalyst

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0357
A New Supported Reagent for the Parallel Synthesis of O-Alkyl Hydroxylamines

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0358
Dynamic Kinetic Resolution of Alcohols by a Racemization Catalyst and a Lipase

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0359
Synthesis of 3-Alkylamino-4,5-disubstituted-1,2,4-triazoles on PEG6000

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0360
Polymer-Micelle Incarcerated (PMI) Scandium as a Polymer-Supported Catalyst

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0361
Polymer-Supported Synthesis of Mono-substituted Porphyrins

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0362
PEG-Supported Imidazolium Chloride for the Heck Reaction

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0363
Mesoporous Silica-Supported Proline Catalysis for Aldol Reaction

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0364
Solid-Phase Enyne Metathesis Using Ruthenium Pre-catalysts

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0365
Solid-Phase Synthesis of Terphenyls

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Supramolecular Chemistry
0367
Formation of Graphitic Nanotubes with One-handed Helical Chirality

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