Synfacts

Ausgabe 11 · November 2006

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Ausgabe
Synthesis of Natural Products and Potential Drugs
1083
Synthesis of (-)-Pironetin

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1084
Synthesis of (+)-Agelastatin A

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1085
Synthesis of (-)-Sordarin

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1086
Synthesis of (-)-Neodysiherbaine

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1087
Synthesis of (-)-Tetrodecamycin

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1088
Synthesis of (+)-Yatakemycin

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1089
Synthesis of (-)-Sarain A

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1090
Synthesis of (-)-Mucocin

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1091
Synthesis of (+)-β-Erythroidine

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1092
Synthesis of Abyssomicin C

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1093
Synthesis of BMS 184394

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1094
Synthesis of (-)-Paroxetine

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1095
Synthesis of a Cathepsin K Inhibitor

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1096
Synthesis of (+)-Machaeriol D

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1097
Synthesis of (-)-(19R)-Ibogamin-19-ol

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Synthesis of Heterocycles
1099
Synthesis of Annulated N-Containing Heterocycles via C-H Activation FREIER ZUGRIFF

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1100
Sulfur Ylide Mediated Asymmetric Synthesis of Aziridines from Sulfinylketimines

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1101
Three-Component Synthesis of 1,2-Dihydroisoquinolines

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1102
One-Pot Synthesis of 3,4-Disubstituted Pyrrole-2-Esters

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1103
Synthesis of Pyrazines from Diaza-butadienes and 1,2-Diamines

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1104
A Classical but Short One-Pot Synthesis of Pyrazoles

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1105
Synthesis of Pyrrolidines from Aminoolefins by Hydroamination

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1106
One-Pot Synthesis of Azaindoles and Indoles

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1107
Synthesis of Tetrahydroquinolines via an Intramolecular Aza-Diels-Alder Reaction

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1108
1,3-Dipolar Cycloaddition Route to Isoxazoline N-Oxides

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1109
One-Pot Synthesis of 2,3-Disubstituted Indoles

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1110
Synthesis of Highly Substituted Imidazoles from Lithiated Methoxyallene

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1111
Cross-Cycloaddition of Two Different Isocyanides to Imidazoles

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1112
Pd-Catalyzed Heteroannulation Route to Polycyclic Indoles

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1113
Synthesis of Carbazoles, Dibenzofurans and -thiophenes via Benzynes

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Synthesis of Materials and Unnatural Products
1115
Activating C-H Bonds Over C-Br Bonds to Make Oligothiophenes

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1116
Switchable Surfactants

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1117
Preparation of Thiaphlorins and Related Dyads

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1118
Synthesis of Oligoesters by Photochemical Reaction

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1119
Synthesizing Higher para-Quinones Using Zirconacyclopentadienes

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1120
Vesicles Formed Thermally and Cross-Linked Ionically

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1121
Organophosphate Sensors by Fluorescent Ligands

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1122
Curved Carbon Fragment of C₆₀ as a Ligand

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1123
Synthesis of Stackable Pseudo-Triphenylenes

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1124
Macrocyclization via Ring-Emitting Covalent Fixation

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1125
Chain Growth of Polymers with Fluorescent Main-Chain Units

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1126
Fluorescence-Based Detection of Nitrating Agents in vivo

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
1127
1,2,3-Triols: Partial Oxidation of γ-Silyl Allylic Alcohols with Ozone FREIER ZUGRIFF

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1128
Cu-Catalyzed Asymmetric S_N2′ Reaction onβ-Disubstituted Allylic Chlorides

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1129
Enantioselective Dialkylzinc Addition to Aldehydes

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1130
Ruthenium-Catalyzed Enzymatic Dynamic Kinetic Resolution of Diols

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1131
Recyclable Ti(IV)/V(V) Catalysts for ChiralO-Acetylcyanohydrin Formation

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1132
Cu(I)-Catalyzed anti-Selective Aminochlorination of Enones

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1133
Enantioselective Allylic Aminations

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1134
A Chiral Tridentate Schiff Base Catalyst for Alkylzinc Addition to Aldehydes

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1135
Air-Stable Zr(IV) Catalysts for Asymmetric Mannich Reactions

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1136
Iridium-Catalyzed Hydrogenation of Olefins and Furan Derivatives

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1137
Reductive Cyclization of Acetylenic Aldehydes via Hydrogenation

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1138
One-Pot Synthesis of Z-Iodoallylic Iodides from Propargyl Alcohols

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1139
Sc(III)-Catalyzed Vinylsilane Addition toN-Phenylglyoxamide

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1140
Asymmetric Synthesis of Propargyl andα-Allenyl Alcohols from Ketones

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1141
3-Component Couplings of α-Oxyaldehydes, Alkynes, and Amines in Water

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1142
Rh-Catalyzed Enantioselective 1,4-Addition of Silyl Boronic Esters

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1143
Stereoselective Synthesis of Epoxyhydroxylamines and 1,2-Oxazetidines

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1144
Mandelamide-Zn-Catalyzed Enantioselective Alkyne Addition to Aldehydes

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1145
Synthesis of Biaryls via Decarboxylative Coupling

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1146
Enantioselective Addition of Vinylzinc Reagents to a Cyclic Nitrone

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1147
Using Rare-Earth Metals for Water-Tolerable Lewis Acid Catalysis

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1148
Rh(I)-Catalyzed Stereoselective Carbocyclization of Alkynals and Alkenes

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1149
Diastereoselective 1,3-Dipolar Cylcoaddition Catalyzed by Silver Acetate

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1150
Unsymmetric BINOL-Titanium Complex for Enantioselective Alkylation

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1151
Stereoselective Synthesis of 1,2,4-Triols from Silylenol Ethers

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1152
Ferrocenyl Imidazoline Palladacycle Catalyzed aza-Claisen Rearrangement

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1153
Co-Catalyzed Reductive Aldol Cyclizations Using Diethylzinc as Reductant

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1154
Fe-Catalyzed Allylic Amination

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Metal-Mediated Synthesis
1155
Co-Catalyzed Hydrohydrazination and Hydroazidation of Olefins FREIER ZUGRIFF

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1156
Radical Functionalization of B-Alkylcatecholboranes

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1157
Synthesis of Quinolines from Acylalkynes and 2-Iodoanilines

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1158
trans-Hydroalumination-Alkylation of Propargylic Alcohols

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1159
Cu-Catalyzed Catalytic Diboration of Aldehydes

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1160
Diarylmethanes from Benzylic Phosphates and Arylmagnesium Halides

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1161
Mn-Mediated Radical Diastereoselective Alkylation of N-Acylhydrazones

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1162
C-Allylation of Propargyl and Benzhydryl Alcohols with Allylsilanes

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1163
Pd-Catalyzed Synthesis of Phenols and Aromatic Ethers from Aryl Halides

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1164
Pd-Catalyzed α-Arylation of Trimethylsilyl Enol Ethers

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1165
Aryl Trihydroxyborates as Convenient Species for Cross-Coupling Reactions

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1166
ZnCl₂-Catalyzed Addition of Grignard Reagents to Ketones and Aldimines

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1167
Cp₂ZrCl₂-DIBAL-H As a Convenient in situ Equivalent to Cp₂ZrHCl

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Organo- and Biocatalysis
1169
Biocatalytic Asymmetric Reduction of Ketones Using Designer Cells FREIER ZUGRIFF

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1170
Conjugate Addition of α,α-Disubstituted Aldehydes to Nitroalkenes

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1171
Organocatalytic Epoxidation Using Hypervalent Iodine Reagents

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1172
Asymmetric Mukaiyama Aldol Reaction Catalyzed by Hydrogen Bonding

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1173
Phase-Transfer-Catalyzed Asymmetric Alkylation of α-Acyl-γ-butyrolactones

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1174
Desymmetrization of meso-Diols via Enantioselective Silylation

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1175
Organocatalytic Asymmetric Kornblum-DeLaMare Rearrangement

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1176
Dynamic Kinetic Resolution of Secondary Alcohols

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1177
Asymmetric Organocatalytic Transfer Hydrogenation of Cyclic Enones

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Polymer-Supported Synthesis
1179
PS-PEG-Supported Aryldicyclohexylphosphine Ligand for Pd-Catalyzed Suzuki Coupling

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1180
An Immobilized Organocatalyst for Cyanosilylation

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1181
Polymer-Support Synthesis of Chiral Tertiary Alcohols

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1182
PEG-Supported Chiral Diamine Ligand for Pd-Catalyzed Allylic Alkylation

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1183
Hydroamination Catalyzed by a Pd Catalyst Immobilized in a Thin Film

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1184
Asymmetric Cyclopropanation Catalyzed by MCF-Supported Bisoxazoline-Cu(I)

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1185
Phosphine Dendrimer-Stabilized Pd Nanoparticles for Suzuki-Miyaura Coupling

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1186
A Polymer-Supported Fe-Zr Catalyst for Dehydrative Esterfication

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1187
Solid Silica Sulfuric Acid (SSA)-Catalyzed Acetylation of Aldehydes and Sugars

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1188
Immobilization of TEMPO onto Polystyrene Resin

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1189
Polymeric DABCO-Bromine Complex for Oxidation of Alcohols

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1190
Self-Supported Noyori-Type Catalysts Using Achiral Bridged-BIPHEPs

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1191
Solid-Phase Synthesis of Tetrahydroβ-carboline Alkaloid

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